1 00:00:46,600 --> 00:00:48,556 ~ PIERRE ARVAY: Music For Solo Harp 2 00:00:50,200 --> 00:00:55,593 There are seven basics shapes of crystals in nature and a multitude of colours. 3 00:00:56,560 --> 00:01:00,838 The crystals in nature express something about the atoms that compose them. 4 00:01:00,920 --> 00:01:03,150 They help to put the atoms into families. 5 00:01:04,160 --> 00:01:10,269 This is the world of physics in our own century, and crystals are a first opening into that world. 6 00:01:12,040 --> 00:01:14,315 ~ KHACHATURIAN: Symphony No.2 "The Bell" 7 00:02:06,680 --> 00:02:11,310 Of all the variety of crystals, the most modest is common salt. 8 00:02:13,040 --> 00:02:15,679 And yet it's surely one of the most important. 9 00:02:20,200 --> 00:02:24,557 This is a small part of the great mine at Wieliczka, 10 00:02:24,640 --> 00:02:27,518 near the ancient Polish capital of Cracow. 11 00:02:34,240 --> 00:02:37,835 Salt has been mined here for nearly a thousand years. 12 00:02:43,320 --> 00:02:47,996 The alchemist Paracelsus may have come this way on his eastern travels. 13 00:02:48,840 --> 00:02:52,549 He changed the course of alchemy after 1500, 14 00:02:52,640 --> 00:02:59,512 by insisting that among the elements that constitute man and nature must be counted salt. 15 00:03:00,720 --> 00:03:07,592 Salt is essential to life and it's always had a symbolic quality in all cultures. 16 00:03:08,840 --> 00:03:13,709 Like the Roman soldiers, we still say "salary" for what we pay a man - 17 00:03:13,800 --> 00:03:15,756 though it means "salt money". 18 00:03:17,400 --> 00:03:20,995 In one respect, Paracelsus was wrong. 19 00:03:21,080 --> 00:03:23,036 Salt is not an element. 20 00:03:24,080 --> 00:03:28,039 Salt is a compound of two elements - sodium and chlorine. 21 00:03:29,000 --> 00:03:34,677 That's remarkable enough that a white fizzy metal, like sodium, 22 00:03:34,760 --> 00:03:37,911 and a yellow poisonous gas like chlorine, 23 00:03:38,000 --> 00:03:43,154 should finish up by making a stable structure - common salt. 24 00:03:44,160 --> 00:03:50,349 But more remarkable is that sodium and chlorine belong to families. 25 00:03:51,080 --> 00:03:56,359 For instance, sodium can certainly be replaced by potassium. 26 00:03:57,360 --> 00:03:59,555 Potassium chloride. 27 00:03:59,640 --> 00:04:05,749 And then, similarly, the chlorine can be replaced by its sister element bromine. 28 00:04:05,840 --> 00:04:07,796 Sodium bromide. 29 00:04:08,640 --> 00:04:10,790 And, finally... 30 00:04:10,880 --> 00:04:13,189 lithium fluoride - 31 00:04:13,280 --> 00:04:18,149 in which sodium has been replaced by lithium, chlorine by fluorine, 32 00:04:18,240 --> 00:04:21,949 and yet all the crystals are indistinguishable. 33 00:04:23,360 --> 00:04:27,399 What makes these family likenesses among the elements? 34 00:04:28,280 --> 00:04:31,750 In the 1860s, everyone was scratching their heads about that. 35 00:04:32,600 --> 00:04:35,637 The man who solved the problem most triumphantly 36 00:04:35,720 --> 00:04:41,158 was a young Russian called Dmitri lvanovich Mendeleev, 37 00:04:41,240 --> 00:04:46,155 who visited the salt mine here at Wieliczka in 1859. 38 00:04:46,240 --> 00:04:48,196 He was 25 then. 39 00:04:48,280 --> 00:04:50,236 A brilliant young man. 40 00:04:51,280 --> 00:04:54,670 The youngest of a vast family of at least 14 children. 41 00:04:54,760 --> 00:04:58,435 The darling of his widowed mother, who drove him through science. 42 00:05:00,640 --> 00:05:08,228 What distinguished Mendeleev was not only genius, but a passion for the elements. 43 00:05:08,320 --> 00:05:10,880 They became his personal friends. 44 00:05:10,960 --> 00:05:13,918 He knew every quirk and detail of their behaviour. 45 00:05:14,680 --> 00:05:22,360 The elements, of course, were distinguished each by only one basic property - 46 00:05:22,440 --> 00:05:25,750 that which John Dalton had posed originally. 47 00:05:25,840 --> 00:05:29,196 Each element has a characteristic atomic weight. 48 00:05:30,640 --> 00:05:36,795 How do the properties that make them alike or different flow from that single gift? 49 00:05:38,280 --> 00:05:40,236 Mendeleev worked at this. 50 00:05:41,120 --> 00:05:44,351 He wrote the elements out on cards, 51 00:05:44,440 --> 00:05:49,912 he shuffled the cards in a game that his friends used to call Patience, 52 00:05:50,000 --> 00:05:54,278 and that is the game that I shall play again. 53 00:05:55,880 --> 00:06:03,275 Mendeleev wrote on his cards the atoms in the order of atomic weights. 54 00:06:03,360 --> 00:06:05,635 Hydrogen he didn 't really know what to do with. 55 00:06:05,720 --> 00:06:08,792 So it's lithium, the lightest that he knew, 56 00:06:09,760 --> 00:06:11,716 then beryllium, 57 00:06:14,480 --> 00:06:16,436 then boron, 58 00:06:18,000 --> 00:06:23,233 then come carbon, nitrogen, oxygen, 59 00:06:24,000 --> 00:06:26,230 and then fluorine. 60 00:06:28,200 --> 00:06:30,555 The next is sodium. 61 00:06:30,640 --> 00:06:35,839 And since that has a family likeness to lithium, we start again up there. 62 00:06:37,400 --> 00:06:46,638 Now, magnesium, aluminium, silicon, phosphorus, sulphur, 63 00:06:46,720 --> 00:06:48,790 and now chlorine. 64 00:06:48,880 --> 00:06:53,908 And sure enough, chlorine stands in the same row as fluorine. 65 00:06:54,000 --> 00:06:56,673 And the next is potassium. 66 00:06:57,640 --> 00:07:05,149 There is potassium, next to lithium, sodium, potassium... calcium. 67 00:07:05,240 --> 00:07:10,712 The fact is that the horizontal rows on this arrangement make sense. 68 00:07:10,800 --> 00:07:12,756 They put families together. 69 00:07:13,520 --> 00:07:20,915 If we arrange in order of atomic weight, get every one, two, three, four, five, six, seven steps, 70 00:07:21,000 --> 00:07:24,993 we start afresh, then we get family arrangements. 71 00:07:26,000 --> 00:07:27,956 And then the first problem. 72 00:07:28,040 --> 00:07:31,953 Because, you see, Mendeleev didn 't have all the elements. 73 00:07:32,040 --> 00:07:37,319 63 out of a total of 92 were known, so sooner or later he was bound to come to gaps. 74 00:07:37,400 --> 00:07:40,153 And the first gap he came to was there 75 00:07:40,240 --> 00:07:44,199 because the next known element, namely titanium, 76 00:07:44,280 --> 00:07:49,957 simply doesn 't have the properties that would fit it there, with boron and aluminium. 77 00:07:50,040 --> 00:07:53,350 So he said, "There's a missing element there. Titanium belongs here." 78 00:07:53,440 --> 00:07:55,874 And indeed it does, with carbon and silicon. 79 00:07:57,680 --> 00:08:01,514 Well, I won 't go on, except just to say that when you go down, 80 00:08:01,600 --> 00:08:04,831 this is where bromine would come in this family likeness. 81 00:08:04,920 --> 00:08:10,392 There were a number of gaps and Mendeleev singled out three. 82 00:08:10,480 --> 00:08:13,199 They stand in these three places. 83 00:08:14,280 --> 00:08:22,631 The one that I've just pointed to... one here in the same row... and one here. 84 00:08:22,720 --> 00:08:28,795 And of them he prophesied that on discovery, they would be found - 85 00:08:28,880 --> 00:08:33,158 not only that they would have the weights that fit into their vertical place, 86 00:08:33,240 --> 00:08:35,390 but that they would have these properties. 87 00:08:35,480 --> 00:08:38,597 For instance, this most famous - 88 00:08:40,280 --> 00:08:42,236 what he called eka-silicon - 89 00:08:44,040 --> 00:08:47,112 he predicted the properties of with great exactitude. 90 00:08:48,000 --> 00:08:50,560 It was nearly 20 years before it was found. 91 00:08:50,640 --> 00:08:55,589 It was found in Germany and called not after Mendeleev but germanium. 92 00:08:57,720 --> 00:09:03,750 Mendeleev had predicted that it would be 5.5 times heavier than water. That was right. 93 00:09:06,880 --> 00:09:12,398 He predicted that its oxide would be 4.7 times heavier than water. That was right. 94 00:09:14,720 --> 00:09:19,840 These forecasts made Mendeleev famous - everywhere except in Russia. 95 00:09:19,920 --> 00:09:24,994 He was not a prophet there because the tsar did not like his liberal politics. 96 00:09:26,840 --> 00:09:30,196 The later discovery of a whole new row of elements 97 00:09:30,280 --> 00:09:33,158 beginning with helium, neon, argon - 98 00:09:33,240 --> 00:09:35,276 enlarged his triumph. 99 00:09:35,360 --> 00:09:40,070 The underlying pattern of the atoms was numerical, that was clear. 100 00:09:41,480 --> 00:09:45,268 And yet that can 't be the whole story. 101 00:09:46,400 --> 00:09:48,994 We must be missing something. 102 00:09:50,040 --> 00:09:56,388 It simply does not make sense to believe that all the properties of the elements 103 00:09:56,480 --> 00:10:00,632 are contained in one number - the atomic weight. 104 00:10:02,240 --> 00:10:04,435 Which hides what? 105 00:10:04,520 --> 00:10:12,154 It must hide some internal structure, some way the atom is physically put together, 106 00:10:12,240 --> 00:10:14,800 which generates those properties. 107 00:10:15,640 --> 00:10:20,236 But, of course, as an idea, that's inconceivable, 108 00:10:20,320 --> 00:10:24,871 so long as it's believed that the atom is indivisible. 109 00:10:25,800 --> 00:10:30,430 And that's why the turning point comes in 1897 110 00:10:30,520 --> 00:10:34,513 when JJ Thomson in Cambridge discovers the electron. 111 00:10:35,720 --> 00:10:39,872 Yes, the atom has constituent parts. 112 00:10:40,800 --> 00:10:44,793 The electron is a tiny part of the mass, but a real part, 113 00:10:44,880 --> 00:10:47,872 and it carries a single electric charge, 114 00:10:48,960 --> 00:10:54,637 and each element is characterised by the number of electrons in its atoms. 115 00:10:54,720 --> 00:11:02,195 And their number is exactly equal to the number of the place in Mendeleev's table 116 00:11:02,280 --> 00:11:04,236 that that element occupies. 117 00:11:05,920 --> 00:11:13,270 The picture has shifted from atomic weight to atomic number. 118 00:11:14,360 --> 00:11:17,750 And that means, essentially, to atomic structure. 119 00:11:20,480 --> 00:11:22,436 Physics becomes, in those years, 120 00:11:24,280 --> 00:11:26,475 the greatest collective work of science. 121 00:11:27,240 --> 00:11:29,037 No - more than that. 122 00:11:29,120 --> 00:11:33,159 The great collective work of art of the 20th century. 123 00:11:33,240 --> 00:11:35,196 ~ MESSIAEN: Works For Organ 124 00:11:47,280 --> 00:11:52,718 I say work of art because the notion that there's an underlying structure, 125 00:11:52,800 --> 00:11:55,234 a world within the world of the atom, 126 00:11:55,320 --> 00:11:58,073 captures the imagination of artists at once. 127 00:12:00,880 --> 00:12:03,519 Since the time of Newton 's Opticks, 128 00:12:03,600 --> 00:12:07,718 painters had been entranced by the coloured surface of things. 129 00:12:09,000 --> 00:12:10,956 The 20th century changed that. 130 00:12:11,840 --> 00:12:17,597 Like the X-ray pictures of Rontgen, it looked for the bone beneath the skin, 131 00:12:17,680 --> 00:12:22,834 and for the deeper, solid structure that builds up from the inside. 132 00:12:22,920 --> 00:12:25,753 The total form of an object or a body. 133 00:12:33,960 --> 00:12:39,193 The Cubist painters, for example, are obviously inspired by the families of crystals. 134 00:12:40,240 --> 00:12:43,630 They see in them the shape of a village on a hillside. 135 00:12:53,400 --> 00:12:57,757 A group of women. This is Pablo Picasso's famous beginning to Cubist painting. 136 00:12:58,880 --> 00:13:00,836 A single face. 137 00:13:02,680 --> 00:13:08,437 The interest has shifted from the skin and the features, to the underlying geometry. 138 00:13:09,360 --> 00:13:12,716 The head has been taken apart into mathematical shapes 139 00:13:12,800 --> 00:13:19,069 and then put together as a reconstruction, a recreation from the inside out. 140 00:13:20,120 --> 00:13:25,433 This new search for the hidden structure is striking in the painters of northern Europe. 141 00:13:25,520 --> 00:13:29,798 Franz Marc, for example, looking at the natural landscape. 142 00:13:29,880 --> 00:13:34,590 And, a favourite with scientists, the Cubist, Jean Metzinger. 143 00:13:38,520 --> 00:13:43,355 There are two clear differences between a work of art and a scientific paper. 144 00:13:44,400 --> 00:13:50,953 One is that in the work of art, the painter is visibly both taking the world to pieces 145 00:13:51,040 --> 00:13:54,476 and putting it together on the same canvas. 146 00:13:56,000 --> 00:14:01,154 And the other is that you can watch him thinking while he's doing it. 147 00:14:04,200 --> 00:14:09,399 In both these respects, the scientific paper is often deficient. 148 00:14:09,480 --> 00:14:11,357 It often is only analytic... 149 00:14:12,400 --> 00:14:18,236 ...and it almost always hides the process of thought in its impersonal language. 150 00:14:20,880 --> 00:14:29,913 I have chosen to talk about one of the founder fathers of 20th-century physics - Niels Bohr - 151 00:14:30,000 --> 00:14:35,996 who collected pictures here in his house in Copenhagen in Denmark, 152 00:14:36,840 --> 00:14:43,075 because in both these respects he was a consummate artist. 153 00:14:44,800 --> 00:14:46,756 He had no ready-made answers. 154 00:14:47,480 --> 00:14:51,359 He used to begin his lecture courses by saying to his students, 155 00:14:51,440 --> 00:15:01,156 "Every sentence that I utter should be regarded by you not as an assertion, but as a question." 156 00:15:04,880 --> 00:15:08,031 What he questioned was the structure of the world. 157 00:15:09,360 --> 00:15:13,592 And the people that he worked with, when young and when old, 158 00:15:15,200 --> 00:15:19,796 were others who were taking the world to pieces, 159 00:15:21,160 --> 00:15:23,720 thinking it out and putting it together. 160 00:15:27,160 --> 00:15:35,670 He went first, in his 20s, to work with Ernest Rutherford, 161 00:15:35,760 --> 00:15:45,158 who, round about 1910, was the outstanding experimental physicist in the world. 162 00:15:45,240 --> 00:15:47,071 Rutherford was then at Manchester, 163 00:15:47,160 --> 00:15:54,316 and in 1911, he proposed a new model for the atom. 164 00:15:55,280 --> 00:16:00,912 He had said the heavy nucleus is at the centre 165 00:16:01,000 --> 00:16:05,755 and the electrons circle it on paths, 166 00:16:05,840 --> 00:16:09,719 the way that the planets circle the sun. 167 00:16:11,640 --> 00:16:18,239 A nice irony of history that, in 300 years, 168 00:16:18,320 --> 00:16:22,757 the outrageous image of Copernicus and Newton 169 00:16:22,840 --> 00:16:28,278 had become the most natural model for every scientist. 170 00:16:33,640 --> 00:16:37,758 Nevertheless, there was something wrong with Rutherford's model. 171 00:16:37,840 --> 00:16:42,834 The planets as they move in their orbits lose energy continuously, 172 00:16:42,920 --> 00:16:46,310 so that year by year, their orbits get smaller - 173 00:16:46,400 --> 00:16:51,155 a very little smaller, but, in time, they will fall into the sun. 174 00:16:51,240 --> 00:16:57,156 If the electrons are exactly like the planets, then they will fall into the nucleus. 175 00:16:58,200 --> 00:17:03,593 There must be something to stop the electrons from losing energy continuously. 176 00:17:04,560 --> 00:17:06,915 That required a new principle in physics 177 00:17:07,000 --> 00:17:11,198 which limits the energy that an electron can give out to fixed values. 178 00:17:13,800 --> 00:17:22,310 Only so can there be a yardstick, a definite unit which holds the electrons to orbits of fixed sizes. 179 00:17:24,480 --> 00:17:30,191 Niels Bohr discovered the unit he was looking for... 180 00:17:32,360 --> 00:17:41,519 ...in the work that Max Planck had published in Germany in 1900. 181 00:17:51,400 --> 00:17:54,597 What Planck had shown, a dozen years earlier, 182 00:17:55,600 --> 00:17:59,957 is that in a world in which matter comes in lumps, 183 00:18:01,000 --> 00:18:05,391 energy must comes in lumps, or quanta, also. 184 00:18:08,280 --> 00:18:10,953 By hindsight, that does not seem so strange. 185 00:18:13,880 --> 00:18:18,954 But Planck knew how revolutionary the idea was the day he had it. 186 00:18:20,000 --> 00:18:26,075 Because on that day he took his little boy for one of those professorial walks and said to him, 187 00:18:27,360 --> 00:18:29,396 "I have had a conception today... 188 00:18:30,440 --> 00:18:36,037 ...as revolutionary and as great as the kind of thought that Newton had." 189 00:18:36,760 --> 00:18:38,398 And so it was. 190 00:18:38,720 --> 00:18:43,316 Now, in a sense, of course, Bohr's task was easy. 191 00:18:43,360 --> 00:18:47,239 He had the Rutherford atom in one hand, he had the quantum in the other. 192 00:18:48,280 --> 00:18:52,671 What was there so wonderful about a young man of 27 in 1913 193 00:18:52,760 --> 00:18:58,118 putting the two together and making the modern image of the atom? 194 00:19:00,520 --> 00:19:03,956 Nothing but the wonderful, visible thought process. 195 00:19:05,280 --> 00:19:07,669 Nothing but the effort of synthesis. 196 00:19:12,560 --> 00:19:17,759 And the support of it, in the one place where it could be found, 197 00:19:19,160 --> 00:19:21,116 the fingerprint of the atom, 198 00:19:22,160 --> 00:19:29,191 the spectrum in which its internal behaviour becomes visible to us looking at it from outside. 199 00:19:30,960 --> 00:19:33,599 That was Bohr's marvellous idea. 200 00:19:34,760 --> 00:19:36,716 The inside of the atom is invisible, 201 00:19:37,600 --> 00:19:40,990 but there is a window in it, a stained-glass window, 202 00:19:41,720 --> 00:19:43,870 the spectrum of the atom. 203 00:19:43,960 --> 00:19:46,394 Each element has its own spectrum. 204 00:19:47,240 --> 00:19:52,439 For example, hydrogen has three rather vivid lines in its visible spectrum. 205 00:19:53,440 --> 00:19:56,557 Bohr explained them as a release of energy 206 00:19:56,640 --> 00:19:59,108 when the single electron in the hydrogen atom 207 00:19:59,200 --> 00:20:02,909 jumps from one of the outer orbits to one of the inner orbits. 208 00:20:10,920 --> 00:20:15,948 The red line is when the electron jumps from the third orbit to the second. 209 00:20:23,360 --> 00:20:28,309 The blue-green line - when the electron jumps from the fourth orbit to the second. 210 00:20:30,320 --> 00:20:34,996 The structure of the atom was now as mathematical as Newton 's universe, 211 00:20:35,080 --> 00:20:38,356 but it contained the additional principle of the quantum. 212 00:20:41,120 --> 00:20:43,918 Niels Bohr had built a world inside the atom 213 00:20:44,000 --> 00:20:49,393 by going beyond the laws of physics as they had stood for two centuries after Newton. 214 00:20:50,360 --> 00:20:53,193 He returned to Copenhagen in triumph. 215 00:20:54,720 --> 00:20:56,676 ~ CARL NIELSEN: Symphony No.2 216 00:21:16,520 --> 00:21:18,750 Denmark was home for him again. 217 00:21:18,840 --> 00:21:20,796 A new place to work. 218 00:21:20,880 --> 00:21:27,752 In 1920, they built the Niels Bohr Institute for him, where it has been ever since. 219 00:21:31,280 --> 00:21:39,676 It's interesting to trace the steps of confirmation of Bohr's model of the atom 220 00:21:39,760 --> 00:21:47,917 because in a way they recapitulate the life cycle of every scientific theory. 221 00:21:49,520 --> 00:21:51,476 First, the paper. 222 00:21:53,240 --> 00:21:59,952 In that, known results are used to support the model. 223 00:22:01,040 --> 00:22:04,635 That is to say, the spectrum of hydrogen in particular... 224 00:22:05,640 --> 00:22:10,316 ...is shown to have lines, long known, 225 00:22:10,400 --> 00:22:16,794 whose positions correspond to quantum transitions of the electrons 226 00:22:16,880 --> 00:22:18,836 from one orbit to another. 227 00:22:20,960 --> 00:22:30,153 The next step is to extend that kind of confirmation to a new phenomenon. 228 00:22:31,080 --> 00:22:36,791 In this case, lines in the higher energy X-ray spectrum. 229 00:22:38,440 --> 00:22:44,310 That work was going on in Rutherford's laboratory in 1913 230 00:22:44,400 --> 00:22:50,748 and yielded beautiful results, exactly confirming what Bohr had predicted. 231 00:22:52,560 --> 00:22:56,030 The man who did that work was Harry Moseley, 232 00:22:56,120 --> 00:23:02,434 who, like Rupert Brooke, died, sadly, at Gallipoli in 1915. 233 00:23:03,600 --> 00:23:08,151 His work, like Mendeleev, suggested some missing elements 234 00:23:08,240 --> 00:23:12,074 and one of them, hafnium, was discovered in Bohr's laboratory. 235 00:23:14,480 --> 00:23:19,395 And just at this moment, when everything seems to be going so swimmingly, 236 00:23:20,400 --> 00:23:29,399 we suddenly begin to realise that the theory is reaching the limits of what it can do. 237 00:23:30,320 --> 00:23:37,396 It begins to develop little cranky weaknesses, a kind of rheumatic pain. 238 00:23:37,480 --> 00:23:41,473 And then... the crucial realisation... 239 00:23:43,560 --> 00:23:51,717 ...that we have not cracked the real problem of atomic structure at all. 240 00:23:53,560 --> 00:23:55,516 We've cracked the shell. 241 00:23:56,720 --> 00:24:04,070 But within that shell, the atom is an egg with a yolk - the nucleus - 242 00:24:05,240 --> 00:24:10,314 and we have not begun to understand the nucleus. 243 00:24:11,440 --> 00:24:13,396 ~ CARL NIELSEN: Serenata In Vano 244 00:24:27,360 --> 00:24:31,273 Niels Bohr was a man with a taste for contemplation and leisure. 245 00:24:33,400 --> 00:24:38,997 When he won the Nobel prize in 1922, he spent the money on buying a house in the country. 246 00:24:40,000 --> 00:24:43,197 His taste for the arts also ran to poetry. 247 00:24:43,280 --> 00:24:49,674 He said to Heisenberg, "When it comes to atoms, language can be used only as poetry. 248 00:24:50,560 --> 00:24:58,148 The poet, too, is not nearly so concerned with describing facts as with creating images." 249 00:24:58,240 --> 00:25:00,549 That's an unexpected thought. 250 00:25:00,640 --> 00:25:07,159 When it comes to atoms, language is not describing facts, but creating images. 251 00:25:08,640 --> 00:25:13,077 But it is so. What lies below the visible world is always imaginary. 252 00:25:13,840 --> 00:25:15,751 A play of images. 253 00:25:15,840 --> 00:25:21,597 There is no other way to talk about the invisible, in nature, in art or in science. 254 00:25:33,360 --> 00:25:36,477 When we step through the gateway of the atom, 255 00:25:36,560 --> 00:25:39,791 we are in a world which our senses cannot experience. 256 00:25:39,880 --> 00:25:41,836 ~ SIBELIUS: Symphony No.6 in D Minor 257 00:25:44,400 --> 00:25:50,475 There's a new architecture there, a way that things are put together which we cannot know. 258 00:25:52,680 --> 00:25:58,277 We only try to picture it by analogy, a new act of imagination. 259 00:26:01,960 --> 00:26:05,999 The architectural images come from the concrete world of our senses 260 00:26:06,080 --> 00:26:09,868 because that's the only world that words describe. 261 00:26:10,760 --> 00:26:16,039 But all our ways of picturing the invisible are metaphors, likenesses, 262 00:26:16,120 --> 00:26:20,671 that we snatch from the larger world of eye and ear and touch. 263 00:26:22,040 --> 00:26:27,160 Once we've discovered that the atoms are not the ultimate building blocks of matter, 264 00:26:27,240 --> 00:26:33,236 we can only try to make models of how the building blocks link and act together. 265 00:26:36,920 --> 00:26:41,516 The models are meant to show, by analogy, how matter is built up. 266 00:26:41,600 --> 00:26:45,513 So, to test the models, we have to take matter to pieces... 267 00:26:50,440 --> 00:26:54,319 ...like the diamond cleaver feeling for the structure of the crystal. 268 00:26:55,600 --> 00:26:59,593 The ascent of man is a richer and richer synthesis. 269 00:27:00,440 --> 00:27:04,991 But each step is an effort of analysis, of deeper analysis. 270 00:27:05,920 --> 00:27:08,070 When the atom was found to be divisible, 271 00:27:08,160 --> 00:27:11,709 it seemed that it might have an indivisible centre, the nucleus. 272 00:27:12,440 --> 00:27:17,673 And now it turned out, around 1930, that the model needed a new refinement. 273 00:27:18,640 --> 00:27:22,679 The nucleus at the centre of the atom is not the ultimate reality either. 274 00:27:25,760 --> 00:27:30,356 (Machinery roars) At twilight on the sixth day of Creation, 275 00:27:30,400 --> 00:27:34,359 so say the Hebrew commentators to the Old Testament, 276 00:27:35,440 --> 00:27:42,198 God made for man a number of tools that give him also the gift of creation. 277 00:27:43,560 --> 00:27:46,996 If the commentators were alive today, they would write... 278 00:27:48,040 --> 00:27:50,156 ..."God made the neutron." 279 00:27:50,920 --> 00:27:56,552 Here it is, the blue glow that is the trace of neutrons, 280 00:27:57,360 --> 00:28:03,151 the visible finger of God touching Adam in Michelangelo's painting 281 00:28:03,240 --> 00:28:06,516 not with breath but with power. 282 00:28:21,120 --> 00:28:23,076 (Thunderclap) 283 00:28:35,320 --> 00:28:39,393 It was James Chadwick who proved in 1932 284 00:28:39,480 --> 00:28:45,589 that the nucleus consists not only of the electrical positive proton, 285 00:28:45,680 --> 00:28:49,753 but of a non -electrical particle - the neutron. 286 00:28:51,200 --> 00:28:54,510 The neutron, therefore, was a new kind of probe, 287 00:28:55,320 --> 00:28:57,834 a sort of alchemist's flame, 288 00:28:59,040 --> 00:29:01,634 because, having no electric charge, 289 00:29:01,720 --> 00:29:05,759 it could be fired at the nuclei of atoms and change them. 290 00:29:06,800 --> 00:29:12,432 The modern alchemist, the man who, more than anyone, took advantage of that, 291 00:29:12,520 --> 00:29:15,353 was Enrico Fermi, in Rome. 292 00:29:18,440 --> 00:29:20,476 Enrico Fermi was a strange creature. 293 00:29:21,440 --> 00:29:27,197 I didn 't know him until much later because in 1934, Rome was in the hands of Mussolini, 294 00:29:27,280 --> 00:29:29,236 Berlin was in the hands of Hitler, 295 00:29:29,320 --> 00:29:31,276 and men like me didn 't travel there. 296 00:29:32,280 --> 00:29:35,795 But when I saw him in New York, much later, 297 00:29:35,880 --> 00:29:39,873 he struck me as the cleverest man I had ever set eyes on. 298 00:29:41,400 --> 00:29:45,188 Well, perhaps the cleverest man with one exception. 299 00:29:46,240 --> 00:29:52,679 Compact, small, powerful, penetrating, very sporty. 300 00:29:53,440 --> 00:29:58,195 And always with the direction in which he was going 301 00:29:58,280 --> 00:30:03,195 as clear in his mind as if he could see to the very bottom of things. 302 00:30:04,280 --> 00:30:09,832 The neutrons he used you can see streaming out of this reactor. 303 00:30:10,800 --> 00:30:17,956 It's a High Flux Isotope Reactor which has been developed here at Oak Ridge. 304 00:30:21,240 --> 00:30:25,711 Transformation was, of course, an age-old dream. 305 00:30:26,760 --> 00:30:30,514 But to men like me with a theoretical bent of mind, 306 00:30:30,600 --> 00:30:38,553 what was most exciting about the period was that it began to open up the evolution of nature. 307 00:30:39,480 --> 00:30:41,436 I must explain that phrase. 308 00:30:42,520 --> 00:30:46,195 I began by talking about the day of Creation and I'll do that again. 309 00:30:47,640 --> 00:30:49,596 Where shall I start? 310 00:30:49,680 --> 00:30:58,315 Bishop Ussher, a long time ago, said that the universe was created in 4004 BC. 311 00:30:58,400 --> 00:31:04,316 Armed as he was with dogma and ignorance, he brooked no rebuttal. 312 00:31:05,320 --> 00:31:11,953 He knew the year, the date, the day of the week, the hour, which, fortunately, I've forgotten. 313 00:31:14,120 --> 00:31:18,079 But the puzzle remained, oh, well into the 1900s, 314 00:31:19,160 --> 00:31:25,838 because while it was very clear that the Earth was many, many millions of years old, 315 00:31:27,160 --> 00:31:30,948 where did the energy come from in the sun and the stars? 316 00:31:32,440 --> 00:31:34,670 We had Einstein 's equations, of course, 317 00:31:34,760 --> 00:31:38,514 which showed that the loss of matter would produce energy, by then. 318 00:31:39,280 --> 00:31:41,236 But how was the matter rearranged? 319 00:31:42,240 --> 00:31:47,519 Well, that's really the understanding that Chadwick's discovery opened. 320 00:31:49,360 --> 00:31:55,674 In 1939, Hans Bethe for the first time explained... 321 00:31:57,840 --> 00:32:00,195 ...in very precise terms... 322 00:32:00,280 --> 00:32:04,478 the transformation of hydrogen to helium in the sun 323 00:32:04,560 --> 00:32:10,032 by which a loss of mass streams out to us as this proud gift of energy. 324 00:32:13,360 --> 00:32:16,909 I speak of these matters with a kind of passion 325 00:32:17,000 --> 00:32:22,916 because, of course, to me they have the quality not of memory but of experience. 326 00:32:23,920 --> 00:32:29,472 Hans Bethe's explanation is as vivid to me as my own wedding day, 327 00:32:30,640 --> 00:32:34,679 and the subsequent steps that followed, as the birth of my own children. 328 00:32:35,680 --> 00:32:42,438 Because what was revealed in the years that followed, and finally sealed in, I suppose, 1956, 329 00:32:43,400 --> 00:32:51,353 is that in all the stars there are going on processes which build up the atoms one by one, 330 00:32:51,440 --> 00:32:55,228 into more and more complex structures. 331 00:32:56,680 --> 00:32:59,513 Matter itself evolves. 332 00:33:00,680 --> 00:33:03,877 The word comes from Darwin and biology, 333 00:33:03,960 --> 00:33:08,795 but it's the word that changed physics in my lifetime. 334 00:33:22,560 --> 00:33:28,829 The first step in the evolution of the elements takes places in young stars such as the sun. 335 00:33:31,280 --> 00:33:36,991 It's the step from hydrogen to helium and it needs the great heat of the interior. 336 00:33:37,080 --> 00:33:40,959 What we see on the surface are only storms produced by that action. 337 00:33:46,760 --> 00:33:53,552 Helium was first identified by a spectrum line during the eclipse of the sun in 1868. 338 00:33:53,640 --> 00:33:57,633 That's why it's called helium. It was not known on earth until then. 339 00:34:13,760 --> 00:34:21,075 What happens in effect is that from time to time a pair of nuclei of hydrogen collide and fuse 340 00:34:21,160 --> 00:34:23,116 to make a nucleus of helium. 341 00:34:49,680 --> 00:34:52,638 In time, the sun will become mostly helium. 342 00:34:53,440 --> 00:34:55,954 And then it'll become a hotter star 343 00:34:56,040 --> 00:35:00,318 in which helium nuclei collide to make heavier atoms in turn. 344 00:35:08,400 --> 00:35:12,279 I've come back briefly to the mine at Wieliczka 345 00:35:12,360 --> 00:35:16,876 because there is a historical contradiction to be explained here. 346 00:35:18,960 --> 00:35:23,875 The elements are being built up in the stars constantly. 347 00:35:24,640 --> 00:35:28,349 And yet we used to think that the universe is running down. 348 00:35:29,440 --> 00:35:31,396 Why? Or how? 349 00:35:33,280 --> 00:35:35,748 The idea that the universe is running down... 350 00:35:36,800 --> 00:35:40,998 ...comes from a simple observation about machines. 351 00:35:56,160 --> 00:36:01,393 Every machine consumes more energy than it renders. 352 00:36:02,600 --> 00:36:07,116 Some of it is wasted in friction, some of it is wasted in wear 353 00:36:07,200 --> 00:36:14,515 and, in more sophisticated machines, it's wasted in other ways in which the energy is degraded. 354 00:36:17,920 --> 00:36:26,191 There is a pool of inaccessible energy into which some of the energy that we put in always runs. 355 00:36:27,240 --> 00:36:30,869 Rudolf Clausius put that into a basic principle. 356 00:36:31,640 --> 00:36:40,719 He said that there is energy which is available and there is energy which is not accessible. 357 00:36:40,800 --> 00:36:42,756 That he called entropy. 358 00:36:43,640 --> 00:36:47,428 And he formulated the famous second law of thermodynamics. 359 00:36:48,360 --> 00:36:50,510 Entropy is always increasing. 360 00:36:50,600 --> 00:36:56,516 In the universe, heat is draining into a sort of lake of equality 361 00:36:56,600 --> 00:36:58,875 in which it is no longer accessible. 362 00:37:01,200 --> 00:37:07,230 That was a nice idea a hundred years ago because then heat was thought of as a fluid. 363 00:37:09,240 --> 00:37:16,032 But heat is not material any more than fire is or any more than life is. 364 00:37:16,800 --> 00:37:20,270 Heat is a random motion of the atoms. 365 00:37:21,240 --> 00:37:27,952 And it was Ludwig Boltzmann in Austria who brilliantly seized on that idea 366 00:37:28,040 --> 00:37:35,594 to give a new interpretation to what happens in this machine or a steam engine or the universe. 367 00:37:37,680 --> 00:37:42,595 When energy is degraded, said Boltzmann, 368 00:37:42,680 --> 00:37:46,719 it is the atoms that assume a more disorderly state 369 00:37:46,800 --> 00:37:50,475 and entropy is a measure of disorder. 370 00:37:51,920 --> 00:37:58,155 It is the probability of the state. He put that quite precisely. 371 00:37:58,240 --> 00:38:04,634 S, the entropy, is to be represented as proportional to the logarithm of W, 372 00:38:04,720 --> 00:38:07,598 the probability of a given state. 373 00:38:09,080 --> 00:38:14,200 Of course, disorderly states are much more probable than orderly states. 374 00:38:14,280 --> 00:38:19,149 So, by and large, any orderly arrangement will run down. 375 00:38:20,120 --> 00:38:24,238 But by and large is not always. 376 00:38:25,400 --> 00:38:30,758 It is not true that orderly states constantly run down to disorder. 377 00:38:32,720 --> 00:38:38,829 It is a statistical law, which means that order will tend to vanish. 378 00:38:39,720 --> 00:38:44,396 But statistics do not say always. 379 00:38:45,120 --> 00:38:49,830 Statistics allow order to be built up in some islands of the universe - 380 00:38:49,920 --> 00:38:56,234 here on earth, in you, in me... and in the stars, in all sorts of places - 381 00:38:56,320 --> 00:38:59,073 while disorder takes over in others. 382 00:39:01,840 --> 00:39:03,796 That's a beautiful conception. 383 00:39:05,600 --> 00:39:08,751 But there is still one question to be asked. 384 00:39:10,840 --> 00:39:20,715 If it's true that... probability has brought us here, 385 00:39:23,720 --> 00:39:29,272 is not the probability so low that we have no right to be here? 386 00:39:30,480 --> 00:39:33,552 People who ask that question, always put it in this way: 387 00:39:34,320 --> 00:39:37,676 Think of all the atoms that make up my body at this moment. 388 00:39:39,360 --> 00:39:45,993 How madly improbable that they should come to this place at this instance and form me. 389 00:39:47,000 --> 00:39:48,797 Yes, indeed. 390 00:39:48,880 --> 00:39:54,477 If that was how it happened, it would not only be improbable, I would be virtually impossible. 391 00:39:56,040 --> 00:39:58,474 But, of course, that's not how nature works. 392 00:40:00,480 --> 00:40:03,074 Nature works by steps 393 00:40:03,160 --> 00:40:11,317 The atoms form molecules, the molecules form bases, the bases form amino acids, 394 00:40:11,400 --> 00:40:15,313 they form proteins, proteins work in cells, 395 00:40:15,400 --> 00:40:19,837 the cells make, first of all, very simple animals and then sophisticated ones - 396 00:40:19,920 --> 00:40:21,797 climbing step by step. 397 00:40:22,560 --> 00:40:29,557 Evolution is the climbing of a ladder from simple to complex by steps, 398 00:40:29,640 --> 00:40:32,029 each of which is stable in itself. 399 00:40:32,120 --> 00:40:35,351 Since this is very much my subject, I have a name for it. 400 00:40:35,440 --> 00:40:38,159 I call it stratified stability. 401 00:40:40,160 --> 00:40:49,319 That is what has brought life, not only here, but constantly up a ladder of increasing complexity, 402 00:40:49,400 --> 00:40:52,119 which is the central problem of evolution. 403 00:40:52,200 --> 00:40:56,352 And now we know that that's true not only of life but of matter. 404 00:40:58,040 --> 00:41:02,477 If the stars had to build a heavy element like iron, 405 00:41:03,120 --> 00:41:05,156 a superheavy element like uranium, 406 00:41:05,240 --> 00:41:08,038 by the instant assembly of all the parts, 407 00:41:08,120 --> 00:41:10,714 it would be virtually impossible. 408 00:41:10,800 --> 00:41:15,749 No, no. A star builds hydrogen to helium. 409 00:41:16,960 --> 00:41:21,238 Then, at another stage, in a different star, 410 00:41:21,320 --> 00:41:25,632 helium is assembled to carbon, to oxygen, to heavier elements 411 00:41:25,720 --> 00:41:33,149 and so step by step up the whole ladder to make the 92 elements in nature. 412 00:41:34,080 --> 00:41:36,036 ~ SIBELIUS: Symphony No.7 in C Major 413 00:41:39,040 --> 00:41:42,476 We can 't copy the processes in the stars as a whole 414 00:41:42,560 --> 00:41:46,030 because we don 't command the immense temperatures 415 00:41:46,120 --> 00:41:48,190 that are needed to fuse most elements. 416 00:41:49,080 --> 00:41:54,871 But we've begun to put our foot on the ladder, to copy the first step from hydrogen to helium. 417 00:41:55,760 --> 00:42:00,754 This is another part of Oak Ridge where the fusion of hydrogen is attempted. 418 00:42:12,680 --> 00:42:16,639 It's hard to recreate the temperature within the sun, of course - 419 00:42:16,720 --> 00:42:18,790 over ten million degrees centigrade - 420 00:42:19,520 --> 00:42:25,675 and it's still harder to make any kind of container that will survive that temperature and trap it, 421 00:42:25,760 --> 00:42:27,716 even for a fraction of a second. 422 00:42:27,800 --> 00:42:30,951 This is a new kind of physics - plasma physics. 423 00:42:31,720 --> 00:42:37,556 Its excitement, yes, and its importance is that it's the physics of nature. 424 00:42:38,320 --> 00:42:44,668 For once, the rearrangements that man makes run, not against the direction of nature, 425 00:42:44,760 --> 00:42:50,630 but along the same steps which nature herself takes in the sun and in the stars. 426 00:42:56,560 --> 00:43:03,318 Immortality and mortality is the contrast on which I end this essay. 427 00:43:05,840 --> 00:43:11,836 Physics in the 20th century is an immortal work. 428 00:43:12,760 --> 00:43:17,356 The human imagination working communally... 429 00:43:18,440 --> 00:43:20,829 ...has produced no monuments to equal it - 430 00:43:20,920 --> 00:43:25,675 not the pyramids, not the lliad, not the ballads, not the cathedrals. 431 00:43:27,760 --> 00:43:30,832 The men who made these conceptions, one after another, 432 00:43:30,920 --> 00:43:34,037 are the pioneering heroes of our age. 433 00:43:35,160 --> 00:43:37,310 Mendeleev shuffling his cards. 434 00:43:38,080 --> 00:43:43,473 JJ Thomson, who overturned the Greek belief that the atom in indivisible. 435 00:43:44,240 --> 00:43:47,789 Rutherford, who turned it into a planetary system. 436 00:43:47,880 --> 00:43:50,713 And Niels Bohr, who made that model work. 437 00:43:51,760 --> 00:43:53,876 Chadwick, who discovered the neutron. 438 00:43:54,640 --> 00:43:58,918 And Fermi, who used it to open up and to transform the nucleus. 439 00:43:59,680 --> 00:44:05,869 And, at the head of them, the iconoclasts. The first founders of the new conceptions. 440 00:44:07,040 --> 00:44:11,830 Max Planck, who gave energy an atomic character like matter. 441 00:44:12,640 --> 00:44:16,952 And Ludwig Boltzmann, to whom more than anyone else 442 00:44:17,040 --> 00:44:22,114 we owe the fact that the atom is as real to us now as our own world. 443 00:44:25,120 --> 00:44:31,992 Who would think that only in 1900 people were battling, 444 00:44:34,400 --> 00:44:36,356 one might say to the death, 445 00:44:37,400 --> 00:44:39,356 whether atoms were real or not? 446 00:44:40,240 --> 00:44:45,394 The great philosopher, Ernst Mach, here in Vienna where I am, said no. 447 00:44:47,440 --> 00:44:50,193 The great chemist, Wilhelm Ostwald, said no. 448 00:44:51,400 --> 00:44:57,714 And only one man... at that critical turn of the century, 449 00:44:58,760 --> 00:45:00,796 stood up for the reality of atoms. 450 00:45:01,640 --> 00:45:03,949 He was Ludwig Boltzmann... 451 00:45:05,080 --> 00:45:08,277 ...at whose memorial I have come to pay homage. 452 00:45:12,280 --> 00:45:16,558 An irascible, extraordinary, difficult man. 453 00:45:16,640 --> 00:45:18,596 An early follower of Darwin. 454 00:45:19,680 --> 00:45:23,753 Quarrelsome and delightful and everything that a human being should be. 455 00:45:30,040 --> 00:45:37,230 The ascent of man teetered on a real intellectual balance at that point... 456 00:45:38,720 --> 00:45:43,714 ...because had anti-atomic doctrines then really won the day... 457 00:45:46,200 --> 00:45:50,955 ...our advance would certainly have been set back by decades and perhaps a hundred years. 458 00:45:51,040 --> 00:45:55,511 And not only in physics, but in biology, which is crucially dependent on that. 459 00:45:58,280 --> 00:46:00,350 Did Boltzmann just argue? No. 460 00:46:02,160 --> 00:46:05,869 He lived and died that passion. 461 00:46:06,840 --> 00:46:12,392 In 1906, at the age of 62, feeling isolated and defeated, 462 00:46:12,480 --> 00:46:15,677 at the very moment when atomic doctrine was going to win, 463 00:46:15,760 --> 00:46:20,311 he thought all was lost... and he committed suicide. 464 00:46:23,120 --> 00:46:27,796 What remains to commemorate him is his immortal formula... 465 00:46:32,480 --> 00:46:34,550 I have no phrase to match Boltzmann 's. 466 00:46:35,800 --> 00:46:40,396 But I will take a quotation from the poet William Blake... 467 00:46:43,440 --> 00:46:48,275 ...who begins the Auguries Of Innocence with four lines. 468 00:46:50,840 --> 00:46:53,354 "To see a world in a grain of sand 469 00:46:53,440 --> 00:46:55,396 And a heaven in a wild flower, 470 00:46:56,320 --> 00:47:00,393 Hold infinity in the palm of your hand 471 00:47:01,600 --> 00:47:03,716 And eternity in an hour." 472 00:47:03,800 --> 00:47:05,756 ~ SIBELIUS: Symphony No.7